| Author | Paim, Lilian Aparecida | |
| Author | Augusti, Daniella Vasconcellos | |
| Author | Dalmazio, Ilza | |
| Author | Alves, Tânia Maria de Almeida | |
| Author | Augusti, Rodinei | |
| Author | Luna, Helmuth Guido Siebald | |
| Access date | 2013-08-06T13:07:36Z | |
| Available date | 2013-08-06T13:07:36Z | |
| Document date | 2005 | |
| Citation | PAIM, Lilian Aparecida et al. Electrospray ionization and tandem mass spectrometry characterization of novel heterotrimetallic Ru(g5-C5H5)(dppf)SnX3 complexes and their heterobimetallic Ru(g 5-C5H5)(dppf)X precursors. Polyhedron, v. 24, p. 1153-1159, 2005. | pt_BR |
| ISSN | 0277-5387 | |
| URI | https://www.arca.fiocruz.br/handle/icict/6758 | |
| Language | eng | pt_BR |
| Publisher | Elsevier | pt_BR |
| Rights | restricted access | pt_BR |
| Title | Electrospray ionization and tandem mass spectrometry characterization of novel heterotrimetallic Ru(g5-C5H5)(dppf)SnX3 complexes and their heterobimetallic Ru(g 5-C5H5)(dppf)X precursors | pt_BR |
| Type | Article | |
| Abstract | Electrospray ionization and tandem mass spectrometry were used to characterize some novel heterotrimetallic complexes Ru(g5-C5H5)(dppf)SnX3(1) (dppf = diphenylphosphine ferrocene; X = Cl, Br) and their heterobimetallic precursors Ru(g5-C5H5)(dppf)X(2) (X = Cl, Br, I, N3). The positive-ion ESI mass spectra of1and2in acetonitrile solution showed the predominant presence of the [Ru(g5-C5H5)(dppf)] + cation (3)ofm/z721. In the positive-ion ESI mass spectrum of the complex Ru(g5 -C5H5)(dppf)N3 (2d), another prominent cation ofm/z735, i.e. [Ru(g5 -C5H5)(dppf)N] + (4), was also observed. Its formation was proposed to occur via the oxidation of the ruthenium atom (RuII!RuIII) followed by the loss of N2. The positive-ion ESI tandem mass spectra of ons 3and4showed mainly fragments formed by neutral losses of C5H5, C6H5and P(C6H5)2. Finally, cation 3was proposed to be the catalytic active species in the single-step conversion of methanol to acetic acid | pt_BR |
| Affilliation | Universidade Federal de Minas Gerais. Departamento de Quımica. Belo Horizonte, MG, Brazil. | pt_BR |
| Affilliation | Universidade Federal de Minas Gerais. Departamento de Quımica. Belo Horizonte, MG, Brazil. | pt_BR |
| Affilliation | Universidade Federal de Minas Gerais. Departamento de Quımica. Belo Horizonte, MG, Brazil. | pt_BR |
| Affilliation | Fundação Oswaldo Cruz. Centro de Pesquisas Rene Rachou. Belo Horizonte, MG, Brazil. | pt_BR |
| Affilliation | Universidade Federal de Minas Gerais. Departamento de Quımica. Belo Horizonte, MG, Brazil. | pt_BR |
| Affilliation | Universidade Federal de Minas Gerais. Departamento de Quımica. Belo Horizonte, MG, Brazil. | pt_BR |
| Subject | Ru–Sn complexes | pt_BR |
| Subject | Electrospray ionization | pt_BR |
| Subject | Ru–Sn–Fe complexes | pt_BR |
| Subject | Tandem mass spectrometry | pt_BR |
| Subject | Transient ionic species | pt_BR |
| Subject | Catalytic activity | pt_BR |
